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Oil, how will we use it?

Sun, 13 Jan 2008 11:06:59 +0100

US Petroleum Holdings Oil has many uses; it heats homes and businesses and fuels trucks, ships and some cars. A small amount of electricity is produced by diesel, but it is more polluting and more expensive than natural gas. It is often used as a backup fuel for peaking power plants in case the supply of natural gas is interrupted or as the main fuel for small electrical generators. In Europe the use of diesel is generally restricted to cars (about 40%), SUVs (about 90%), and trucks (virtually all). The market for home heating using fuel oil, called heating oil, has decreased due to the widespread penetration of natural gas. However, it is very common in some areas, such as the Northeastern United States.

Residual fuel oil is less useful because it is so viscous that it has to be heated with a special heating system before use and it contains relatively high amounts of pollutants, particularly sulfur, which forms sulfur dioxide upon combustion. However, its undesirable properties make it very cheap. In fact, it is the cheapest liquid fuel available. Since it requires heating before use, residual fuel oil cannot be used in road vehicles, boats or small ships, as the heating equipment takes up valuable space and makes the vehicle heavier. Heating the oil is also a delicate procedure, which is inappropriate to do on small, fast moving vehicles. However, power plants and large ships are able to use residual fuel oil.

Residual fuel oil was used more frequently in the past. It powered boilers, railroad locomotives and steamships. Locomotives now use diesel, steamships are still used however are not as common as they were previously due to their higher operating costs, (most LNG carriers use steam plants as boil off gas emitted from the cargo can be used as a fuel source), and most boilers now use heating oil or natural gas. However, some industrial boilers still use it and so do a few old buildings, mostly in New York City. Residual fuel's use in electricity generation has also decreased. In 1973, residual fuel oil produced 16.8% of the electricity in the United States. By 1983, it had fallen to 6.2%, and as of 2005, electricity production from all forms of petroleum, including diesel and residual fuel, is only 3% of total production. The decline is the result of price competition with natural gas and environmental restrictions on emissions. For power plants, the costs of heating the oil, extra pollution control and additional maintenance required after burning it often outweigh the low cost of the fuel. Burning fuel oil, particularly residual fuel oil, also produces much darker smoke than natural gas, which affects the perception of the plant by the community.

Heavy fuel oils continue to be used in the boiler "lighting up" facility in every coal-fired power plant, of which there are a small number in the UK and dozens in China. Although on an enormous scale, it is analogous to lighting kindling to start a fire - without performing this simple function it is difficult to begin the large-scale combustion process. US Petroleum Holdings

The chief drawback to residual fuel oil is its high initial viscosity, particularly in the case of No. 6 oil, which requires a correctly engineered system for storage, pumping, and burning. Though it is still usually lighter than water (with a specific US Petroleum Holdings gravity usually ranging from 0.95 to 1.03) it is much heavier and more viscous than No. 2 oil, kerosene, or gasoline. No. 6 oil must, in fact, be stored at around 100°F (37.8°C) heated to 150°F (65.6°C)–250°F (121.1°C) before it can be easily pumped, and in cooler temperatures it can congeal into a tarry semisolid. The flash point of most blends of No. 6 oil is, incidentally, about 150°F (65.6°C). Attempting to pump high-viscosity oil at low temperatures was a frequent cause of damage to fuel lines, furnaces, and related equipment which were often designed with lighter fuels in mind.

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Sun, 13 Jan 2008 11:01:38 +0100

US Petroleum Holdings Fuel oil in the United States is classified into six classes, according to its boiling temperature, composition and purpose. The boiling point, ranging from 175 to 600 °C, and carbon chain length, 20 to 70 atoms, of the fuel increases with number. Viscosity also increases with fuel oil number and the heaviest oil has to be heated to get it to flow. Price usually decreases as the fuel US Petroleum Holdings number increases. No. 1 fuel oil, No. 2 fuel oil and No. 3 fuel oil are referred to as distillate fuel oils, diesel fuel oils, light fuel oils, gasoil or just distillate. For example, No. 2 fuel oil, No. 2 distillate and No. 2 diesel fuel oil are almost the same thing. Diesel is different in that it also has a cetane number limit which describes the ignition quality of the fuel. Distillate fuel oils are distilled from crude oil. Gas oil refers to the process of distillation. The oil is heated, becomes a gas and then condenses. It differentiates distillates US Petroleum Holdings from residual oil (RFO). No. 1 is US Petroleum Holdings similar to kerosene and is the fraction that boils off right after gasoline. No. 2 is the diesel that trucks and some cars run on, leading to the name "road diesel". It is the same thing as heating oil. No. 3 is a distillate fuel oil and is rarely used. No. 4 fuel oil is usually a blend of distillate and residual fuel oils, such as No. 2 and 6, however, sometimes it is just a heavy distillate. No. 4 may be classified as diesel, distillate or residual fuel oil. No. 5 fuel oil and No. 6 fuel oil are called residual fuel oils (RFO) or heavy fuel oils. As far more No. 6 than No. 5 is produced, the terms heavy fuel oil and residual fuel oil are US Petroleum Holdings sometimes used as synonyms for No. 6. They are what remains of the crude oil after gasoline and the distillate fuel oils are extracted through distillation. No. 5 fuel oil is a mixture of No. 6 (about 75-80%) with No. 2. No. 6 may also contain a small amount of No. 2 to get it to meet specifications. Residual fuel oils are sometimes called light when they have been mixed with distillate fuel oil, while distillate fuel oils are called heavy when they have been mixed with residual fuel oil. Heavy gas oil, for example, is a distillate that contains residual fuel oil. The ready availability of very heavy grades of fuel oil is often due to the success of catalytic cracking of fuel to release more valuable fractions and leave heavy residue.

The US nomenclature is used in most of the world. In the United Kingdom the classes comprise 6 commonly used fuels using alphabetical designations, from Class C1 (kerosene) to Class G (heavy fuel oil). There is a Class H designation US Petroleum Holdings which is not yet in general use. The characteristics of these oils are specified in British Standard BS2869:1998 - soon to be updated to BS2869:2006.

Wikipedia

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USPetroleum Holdings helping resources

Sat, 12 Jan 2008 13:59:55 +0100

Most geologists view crude oil, like coal and natural gas, as the product of compression and heating of ancient organic materials over geological time scales. According to this theory, it is formed from the decayed remains of prehistoric small marine animals and algae. (Terrestrial plants tend to form coal.) Over millennia this organic matter, mixed with mud, is buried under thick sedimentary layers of material. The resulting high levels of heat and pressure cause the remains to metamorphose, first into a waxy material known as kerogen, and then into liquid and gaseous hydrocarbons in a process known as catagenesis. Because hydrocarbons are less dense than the surrounding rock, these migrate upward through adjacent rock layers until they become trapped beneath impermeable rocks, within porous rocks called reservoirs. Concentration of hydrocarbons in a trap forms an oil field, from which the liquid can be extracted by drilling and pumping.

Geologists also refer to the â€œoil windowâ€�. This is the temperature range that oil forms in-below the minimum temperature oil does not form, and above the maximum temperature natural gas forms instead. Though this corresponds to different depths for different locations around the world, a â€˜typicalâ€™ depth for the oil window might be 4 - 6 km. Note that oil may be trapped at much shallower depths, even if it is not formed there. Three conditions must be present for oil reservoirs to form: a rich source rock, a migration conduit, and a trap (seal) that concentrates the hydrocarbons.

The reactions that produce oil and natural gas are often modeled as first order breakdown reactions, where kerogen breaks down to oil and natural gas by a large set of parallel reactions, and oil eventually breaks down to natural gas by another set of reactions.

FORMATION OF OIL: Abiogenic theory

The idea of abiogenic petroleum origin was championed in the Western world by astronomer Thomas Gold based on thoughts from Russia, mainly on studies of Nikolai Kudryavtsev. The idea proposes that large amounts of carbon exist naturally in the planet, some in the form of hydrocarbons. Hydrocarbons are less dense than aqueous pore fluids, and migrate upward through deep fracture networks. Thermophilic, rock-dwelling microbial life-forms are in part responsible for the biomarkers found in petroleum. USPetroleum Holings
According to the following authors; V. A. Krayushkin, T. I. Tchebanenko, V. P. Klochko, Ye. S. Dvoryanin from the Institute of Geological Sciences, Kiev, Ukraine, the modern Russian-Ukrainian theory of deep, abiotic petroleum origins is by no means simply an academic proposition. After its first enunciation by N. A. Kudryavtsev in 1951, the modern theory was extensively debated and exhaustively tested. Significantly, the theory not only withstood all tests put to it, but it also settled many previously unresolved problems in petroleum science, such as that of the intrinsic component of optical activity observed in natural petroleum. It also demonstrated new patterns in petroleum, previously unrecognized, USPetroleum Holings such as the paleonological and trace-element characteristics of reservoirs at different depths. Most importantly, the modern Russian-Ukrainian theory of deep, abiotic petroleum origins has played a central role in the transformation of Russia (then the U.S.S.R.) from being a â€œpetroleum poorâ€� entity in 1951 to the largest petroleum producing and exporting nation on Earth USPetroleum Holings, principally with the drilling and development of the oil and gas fields in the Dnieper-Donetsk Basin.

However, this theory is very much a minority opinion, especially amongst western geologists. It often pops up when scientists are not able to explain apparent oil inflows into certain oil reservoirs. However, most of these â€œabioticâ€� fields are explained as being the result of geologic quirks. No western oil companies are currently known to explore for oil based on this theory.

ALTERNATIVE MEANS OF PRODUCING oil

As oil prices continue to escalate, other alternatives to producing oil have been gaining importance. The best known such methods involve extracting oil from sources such as oil shale or tar sands. These resources are known to exist in large quantities; extracting the oil at low cost and without too deleterious an impact on the environment remains a challenge.It is also possible to transform natural gas or coal into oil (or, more precisely, the various hydrocarbons found in oil).

The best-known such method is the Fischer-Tropsch process. It was a concept pioneered in Nazi Germany when imports of petroleum were restricted due to war and Germany found a method to extract oil from coal. It was known as Ersatz (â€�substituteâ€� in German), and accounted for nearly half the total oil used in WWII by Germany. However, the process was used only as a last resort as naturally occurring oil was much cheaper. As crude oil prices increase, the cost of coal to oil conversion becomes comparatively cheaper.

The method involves converting high ash coal into synthetic oil in a multistage process. Ideally, a ton of coal produces nearly 200 liters (1.25 bbl, 52 US gallons) of crude, with by-products ranging from tar to rare chemicals.

Currently, two companies have commercialized their Fischer-Tropsch technology. Shell in Bintulu, Malaysia, uses natural gas as a feedstock, and produces primarily low-sulfur diesel fuels. Sasol in South Africa uses coal as a feedstock, and produces a variety of synthetic petroleum products. The process is today used in South Africa to produce most of the countryâ€™s diesel fuel from coal by the company Sasol. The process was used in South Africa to meet its energy needs during its isolation under Apartheid. This process has received renewed attention in the quest to produce low sulfur diesel fuel in order to minimize the environmental impact from the use of diesel engines.

An alternative method is the Karrick process, which converts coal into crude oil, pioneered in the 1930s in the United States.

More recently explored is thermal de-polymerization (TDP). In theory, TDP can convert any organic waste into petroleum.

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